| Anno | Partita | Serie |
| 1942/43 | SIENA-NAPOLI 0-2 | B |
| 1942/43 | NAPOLI-SIENA 3-2 | B |
| 1945/46 | SIENA-NAPOLI 1-4 | A-B |
| 1945/46 | NAPOLI-SIENA 6-1 | A-B |
| 2001/02 | SIENA-NAPOLI 2-1 | B |
| 2001/02 | NAPOLI-SIENA 2-0 | B |
| 2002/03 | SIENA-NAPOLI 2-0 | B |
| 2002/03 | NAPOLI-SIENA 1-2 | B |
| 2007/08 | SIENA-NAPOLI 1-1 | A |
| 2007/08 | NAPOLI-SIENA 0-0 | A |
